(中南大學(xué) 粉末冶金國家重點(diǎn)實(shí)驗(yàn)室,長沙 410083)
摘 要: 介電電容器因具有功率密度高、充放電速度快和循環(huán)壽命長等優(yōu)點(diǎn),在脈沖功率武器裝備、輸變電工程和5G通訊等方面具有廣闊的應(yīng)用前景。聚丙烯(PP)具有高抗擊穿強(qiáng)度、低介電損耗和良好的可加工性,是目前商業(yè)應(yīng)用最廣泛的介電材料之一,但其介電常數(shù)低,儲能密度難以提高,很大程度上限制其應(yīng)用。基于PP的復(fù)合或者改性可以有效提高其儲能密度,因而成為當(dāng)前的研究熱點(diǎn)。本文綜述近年來介電復(fù)合材料的分類和存在的問題,將填料/聚合物復(fù)合材料和全有機(jī)復(fù)合材料兩種合成策略與PP的儲能性能提升聯(lián)系起來,從無機(jī)陶瓷填料/PP、導(dǎo)電填料/PP、核-殼結(jié)構(gòu)填料/PP、三元復(fù)合材料、交聯(lián)、共混、多層結(jié)構(gòu)設(shè)計(jì)等方面重點(diǎn)討論P(yáng)P基介電復(fù)合材料的研究進(jìn)展。最后總結(jié)開發(fā)高性能PP基介電復(fù)合材料面臨的挑戰(zhàn),對未來研究進(jìn)行展望。
關(guān)鍵字: 聚丙烯;儲能;介電復(fù)合材料
(State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China)
Abstract:Dielectric capacitors have the advantages of high power density, fast charge and discharge speed, and long cycle life. Therefore, they have broad application prospects in pulse power weapon equipment, power transmission and transformation engineering, and 5G communications. Polypropylene (PP) is one of the most widely used dielectric materials in commercial applications at present, which has high breakdown strength, low dielectric loss and good processability. Nevertheless, its dielectric constant is relatively low, which makes it hard to increase the energy storage density. This disadvantage greatly limits the applications of PP. The composite or modification based on PP can effectively enhance the energy storage density, thus becoming a hot research topic. This paper reviews the classification and existing problems of dielectric composites in recent years, linking the two synthesis strategies of filler/polymer composites and all-organic composites with the improvement of the energy storage performance of PP, and focuses on the research progress of PP-based dielectric composites from the aspects of inorganic ceramic fillers/PP, conductive fillers/PP, core-shell structured fillers/PP, ternary composites, cross-linking, blending, design of multilayer structure, etc. Finally, the challenges for developing high-performance PP-based dielectric composites and the prospects for future research directions were summarized.
Key words: polypropylene; energy storage; dielectric composites


