(1. 南昌航空大學(xué) 輕合金加工科學(xué)與技術(shù)國防重點(diǎn)學(xué)科實(shí)驗(yàn)室，南昌 330063；
2. 太原理工大學(xué) 先進(jìn)鎂基材料山西省重點(diǎn)實(shí)驗(yàn)室，太原 030024)
摘 要: 采用攪拌摩擦加工法制備CNTs/7075鋁基復(fù)合材料，測量并分析加工態(tài)、熱處理態(tài)試樣的熱膨脹系數(shù)，并分別用ROM、Turner和Schapery模型進(jìn)行理論計(jì)算。結(jié)果表明：攪拌摩擦加工后材料的晶粒細(xì)小，CNTs的添加能進(jìn)一步細(xì)化晶粒。CNTs/7075復(fù)合材料的熱膨脹系數(shù)低于退火態(tài)和攪拌摩擦加工后7075鋁合金試樣的，說明攪拌摩擦加工對材料晶粒的細(xì)化及CNTs的加入可以有效地約束基體材料的熱膨脹，且隨著CNTs含量的增加，復(fù)合材料的線膨脹系數(shù)呈減小趨勢。后續(xù)熱處理對CNTs/7075復(fù)合材料的熱膨脹系數(shù)也有影響，退火和固溶時(shí)效處理均可以降低該復(fù)合材料的熱膨脹系數(shù)。理論計(jì)算發(fā)現(xiàn)，Turner模型計(jì)算得到的熱膨脹系數(shù)預(yù)測值最接近于實(shí)測值。
關(guān)鍵字: 碳納米管；復(fù)合材料；攪拌摩擦加工；熱膨脹
（1. National Defense Key Disciplines Laboratory of Light Alloy Processing Science and Technology, Nanchang Hangkong University, Nanchang 330063, China;
2. Shanxi Key Laboratory of Advanced Magnesium-based Materials, Taiyuan University of Technology, Taiyuan 030024, China）
Abstract:7075 aluminum alloy based composite reinforced with carbon nanotubes was prepared by friction stir processing. The thermal expansion coefficients of CNTs/7075 composites with processed state and heat treatment were measured. And the theoretical thermal expansion coefficient of CNTs/7075 composite was calculated with ROM, Turner and Schapery’s model. The results show that the grain size of material can effectively reduced by friction stir processing, and the addition of CNTs can further refine grain size of composite. The CNTs/7075 composite has smaller thermal expansion coefficients compared with annealed 7075 matrix materials and the FSPed 7075 samples, which indicates that the addition of CNTs can effectively constrain the thermal expansion of the composite. The thermal expansion coefficients of CNTs/7075 composite samples decrease along with the increase of volume fraction of CNTs. Heat treatment has a positive effect on the thermal expansion characteristic of the composite, and the annealing or aging treatment can decrease the thermal expansion of the composite. The theoretical calculation shows that thermal expansion coefficient of CNTs/7075 composite with Turner’s model is the closest to the experimental result.
Key words: carbon nanotubes; composite; friction stir processing; thermal expansion
