(1. 東莞理工學(xué)院 機(jī)械工程學(xué)院，東莞 523808；
2. 廣東工業(yè)大學(xué) 材料與能源學(xué)院，廣州 510006)
摘 要: 采用單輥急冷法制備一系列不同Co/Ni摩爾比的FeCoNiCrZr非晶薄帶，并對(duì)該系非晶合金進(jìn)行等溫?zé)崽幚怼２捎肵射線衍射儀(XRD)和振動(dòng)樣品磁強(qiáng)計(jì)(VSM)研究Co/Ni摩爾比的變化對(duì)(Fe0.52Co0.48-xNix)73Cr17Zr10系非晶合金的晶化過程和磁性能的影響。結(jié)果表明：x在0.06~0.30之間變化時(shí)，所制備的合金薄帶基本為非晶結(jié)構(gòu)；(Fe0.52Co0.48-xNix)73Cr17Zr10(x=0.18,0.30)兩種非晶合金的晶化過程為Am→α-Fe(Co)+Am′→α-Fe(Co)+Cr2Ni3+ Fe3Ni2+Cr2Zr+未知相；Co/Ni摩爾比的增加增強(qiáng)了合金的熱穩(wěn)定性，抑制了退火后α-Fe(Co)相的析出。兩種合金的飽和磁化強(qiáng)度Ms隨退火溫度的變化趨勢(shì)相同，在低于第一晶化峰值溫度θp1退火時(shí)，Ms隨退火溫度的升高逐步上升；在溫度高于Tp1退火時(shí)，Ms隨退火溫度的升高而迅速下降。
關(guān)鍵字: 非晶合金；熱處理；晶化過程；磁性能
（1. School of Mechanical Engineering, Dongguan University of Technology, Dongguan 523808, China;
2. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China）
Abstract:FeCoNiCrZr amorphous ribbons with different Co/Ni mole ratio were prepared by melt-spun method and the amorphous alloys were studied using isothermal heat treatment. X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) were used to study the effects of Co/Ni mole ratio on the crystallization processes and magnetic properties of (Fe0.52Co0.48-xNix)73Cr17Zr10 amorphous ribbons.The results show that when x in the range of 0.06 to 0.30, the ribbons are in an amorphous state. The crystallization process of (Fe0.52Co0.30Ni0.18)73Cr17Zr10 is the same as (Fe0.52Co0.18Ni0.30)73Cr17Zr10:Am→α-Fe(Co)+Am''''→α-Fe(Co)+Cr2Ni3+Fe3Ni2+Cr2Zr+unidentified phase. With increasing Co/Ni mole ratio, the thermal stability of the alloys is enhanced and the precipitation of α-Fe(Co) after annealing is restrained. The changing trends of magnetic properties of the two alloys are the same with increasing annealing temperature. When the annealed temperature is below Tp1, saturation magnetization Ms increases with increasing annealing temperature; when the annealed temperatures is over Tp1, Ms decreases quickly with increasing annealing temperature.
Key words: amorphous alloys; heat treatment; crystallization processes; magnetic properties
