Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 24    No. 2    February 2014

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Chemical fractionation method for characterization of biomass-based bottom and fly ash fractions from large-sized power plant of an integrated pulp and paper mill complex
Risto P?YKI?1, Hannu NURMESNIEMI2, Olli DAHL3, Mikko M?KEL?4

1. City of Kemi, Valtakatu 26, FI-94100 Kemi, Finland;
2. Stora Enso Oyj, Veitsiluoto Mill, FI-94800 Kemi, Finland;
3. Department of Forest Products Technology, School of Chemical Technology, Aalto University,
P. O. Box 16300, FI-00076 Aalto, Finland;
4. Division of Biomass Technology and Chemistry, Department of Forest Biomaterials and Technology,
Swedish University of Agricultural Sciences, P.O. Box SLU, SE-90183 Ume?, Sweden

Abstract:The aim of this study was to extract the biomass-based bottom and fly ash fractions by a three-stage fractionation method for water-soluble (H2O), ammonium-acetate (CH3COONH4) and hydrochloric acid (HCl) fractions in order to access the leaching behaviour of these residues. Except for Mo, S, Na and elements whose concentrations were lower than the detection limits, the extractable element concentrations in both ash fractions followed the order H2O<CH3COONH4<HCl. The elements concentrations in this study were also lower than those in our previous studies, in which certain extraction stages followed the BCR extraction procedure.

 

Key words: ash; extraction; forest industry; landfilling; leaching; heavy metals; waste

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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