(中南工業(yè)大學(xué)化學(xué)系過程分析中心,長沙410083)
摘 要: 利用流動注射分析(FIA)的流通分光光度法,結(jié)合梯度稀釋技術(shù),在非平衡條件下,僅用中心離子和配體各一個標(biāo)準(zhǔn)濟(jì)液測定絡(luò)合物的組成,方法簡單。測定了幾組二元及三元絡(luò)合物體系,其結(jié)果令人滿意。
關(guān)鍵字: 流通分光光度法 梯度稀釋 絡(luò)合物組成
OF COMPOSITION OF COMPLEXES
(Department of Chemistry,Process Analysis Center,
Central South University of Technology,Changsha 410083)
Abstract:Based on flow injection analysis (FIA), a flow-spectrophotometric method has been developed for the determination of composition of complexes with single standard gradient techniques under non-equilibrium state. Only one central ion standard solution and one coordinator standard solution are needed in this simple method. Satisfactory results have been obtained for the composition of some binary and tertiary complex systems.
Key words: flow-spectrophotometry gradient-dilution composition of complex


