(1.河北師范大學(xué)化學(xué)系, 石家莊 050016;
2.河北聯(lián)合制藥廠,石家莊 050021)
摘 要: 給出了M-H2O體系中M化合物Mi 的熱力學(xué)相對穩(wěn)定性指數(shù)DMi變量,提供了 在三維空間分析Pourbaix圖結(jié)構(gòu)的可能性,進而給出了亞穩(wěn)態(tài)物質(zhì)在φ—pH面上的分布 方程。采用“兩步法” 步驟編制了繪制常溫條件下亞穩(wěn)態(tài)物質(zhì)的φ—pH圖的通用電算程序,給出了計算示例和應(yīng)用分析。
關(guān)鍵字: Pourbaix圖 熱力學(xué)穩(wěn)定性指數(shù) 亞穩(wěn)態(tài)物質(zhì) φ—pH 圖
(1.Department of Chemistry, Hebei Normal University, Shijiazhuang 050016;
2.Hebei Unipharm Co. Ltd., Shijiazhuang 050021)
Abstract:The thermodynamical stability order of Mi in M-H2 O system was discussed. A distributing equation of metastable substances was given . The φ—pH diagrams for Mn-H2O and Cu-H2O systems were described as examples.
Key words: Pourbaix diagram thermodynamical stability order
distributing equation of metastable substances


