(大連理工大學(xué) 材料工程系， 大連 116024)
摘 要: Zn的活潑性使Sn-9Zn無(wú)鉛釬料的潤(rùn)濕性和抗氧化性很差， 在Sn-9Zn合金中加入適量混合稀土元素(Ce, La)可以改善其潤(rùn)濕性能。分別在245， 260和290℃通過(guò)潤(rùn)濕平衡實(shí)驗(yàn)對(duì)釬料的潤(rùn)濕性進(jìn)行了研究， 并對(duì)RA, RMA, R和WWR 4種不同釬劑進(jìn)行了比較。 結(jié)果表明： 在運(yùn)用活性松香釬劑時(shí)，微量混合稀土元素可以顯著提高Sn-9Zn合金潤(rùn)濕性； 而提高釬焊溫度也可以改善潤(rùn)濕性能。
關(guān)鍵字: 無(wú)鉛釬料； 稀土； Sn-9Zn； 潤(rùn)濕性
trace rare earth elements
（Department of Materials Engineering, Dalian University of Technology,
Dalian 116024, China）
Abstract:The eutectic Sn-9Zn alloy is one of the lead-free solder alloys at the present time. Since Zn is an active element in solder, the wetting and corrosion properties of Sn-9Zn alloy are impaired. In order to improve the wetting behavior, trace rare earth elements were added into Sn-9Zn alloy. The wetting balance tests were conducted in ambient air to reveal the wetting behavior. Several types of flux, i.e. RA, RMA, R and WWR, were used to study the wetting properties of the Sn-9Zn-RE alloy system at 245, 260 and 290℃, respectively. By using RA flux, the trace RE addition can improve the wetting behavior significantly and the increasing of the temperature can also improve the properties.
Key words: lead-free solder; rare earth element; Sn-9Zn; wettability
