( 1. 中國科學(xué)院 金屬研究所, 沈陽 110016;
2. Ris國家實(shí)驗(yàn)室, Roskilde DK-4000, 丹麥)
摘 要: 研究了Mg60Cu30Y10大塊非晶合金在過冷液相區(qū)的流變行為。 結(jié)果表明: 隨著溫度升高和應(yīng)變速率增加, 平衡態(tài)的牛頓流轉(zhuǎn)變?yōu)榉瞧胶鈶B(tài)的非牛頓流; 其流變行為對于溫度和應(yīng)變速率非常敏感。 由粘度與應(yīng)變速率的關(guān)系, 根據(jù)Arrhenius型VFT方程, 確定了流動應(yīng)力、 應(yīng)變速率和溫度的關(guān)系。 Mg60Cu30Y10大塊非晶合金在過冷液相區(qū)的流變性能依賴于溫度與變形速率, 其微觀機(jī)制可由自由體積模型解釋, 為大塊非晶合金流變成形工藝的實(shí)現(xiàn)提供理論依據(jù): 溫度高于玻璃轉(zhuǎn)變溫度以后, 自由體積的增加使非晶合金變形過程中能夠移動的原子數(shù)目隨之增加, 自由體積周圍的原子沿外力的作用方向移動, 即宏觀上的塑性流變行為。 應(yīng)變速率增加, 由熱激活引起的自由體積增加不能滿足更多原子流變所需的空間體積, 導(dǎo)致牛頓流向非牛頓流轉(zhuǎn)變。
關(guān)鍵字: 鎂基大塊非晶; 過冷液相區(qū); 流變行為; 本構(gòu)關(guān)系
( 1. Institute of Metal Research, Chinese Academy of Sciences,
Shenyang 110016, China;
2. Risφ National Laboratory, Roskilde DK-4000, Denmark)
Abstract: Viscous flow behavior of Mg60Cu30Y10 bulk metallic glass in supercooled liquid region was investigated. The supercooled liquids exhibit that Newtonian viscosity in equilibrium state transforms to a non-Newtonian viscosity in non-equilibrium state with temperature and strain rate increasing. According to VFT (Vogel-Fulcher-Tammann) equation with the Arrhenius function, the relation between flow stress and viscosity and temperature was established. Viscous flow of Mg60Cu30Y10 bulk metallic glass depends on temperature and strain rate. It can be described with the free-volume model and used to interpret the implement of Mg-based bulk metallic glass viscous forming process. When the temperature is higher than glass transition temperature, the number of atoms which can jump during deformation of bulk metallic glass increases. Atomic jumps are biased in the direction of the external force. This forms the plastic flow showed in macroscopic. With strain rate increasing, free volume obtained from thermal fluctuations can't meet the need of more and more atomic jumps. It results in steady state Newtonian viscosity transfer to non-Newtonian viscosity.
Key words: Mg-based bulk metallic glass; supercooled liquid region; viscous flow behavior; constitutive equation


