Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號(hào):1004-0609(2008)10-1945-06
生物吸附-沉降法去除電鍍廢水中鎘
代淑娟1,魏德洲1,白麗梅2,周東琴1,王玉娟1,劉文剛1

(1. 東北大學(xué) 資源與土木工程學(xué)院,沈陽 110004;
2. 河北理工大學(xué) 資源與環(huán)境學(xué)院,唐山 063009
)

摘 要:

以水洗廢啤酒酵母為吸附劑,采用吸附−沉降法,研究水洗廢啤酒酵母對(duì)電鍍廢水中鎘的吸附規(guī)律及沉降效果。結(jié)果表明, 在廢水中鎘含量為26 mg/L、pH 7、水洗廢啤酒酵母用量40 g/L(含水約72%)、室溫(約18 ℃)、攪拌速度800 r/min、吸附時(shí)間30 min、沉降3.5 h的條件下,廢水中鎘的吸附率及吸附−沉降后鎘的去除率均達(dá)96%以上。并采用透射電子顯微鏡、電動(dòng)電位及紅外光譜分析手段,分析水洗廢啤酒酵母對(duì)鎘的吸附機(jī)理。水洗廢啤酒酵母對(duì)鎘的吸附不僅發(fā)生菌體表面,也發(fā)生在菌體內(nèi)部。吸附過程存在化學(xué)絡(luò)合、靜電吸引、氫鍵等作用。

 

關(guān)鍵字: 電鍍廢水;鎘;水洗廢啤酒酵母;生物吸附;沉降

Removing cadmium from cadmium-containing electroplating wastewater by biosorption-sedimentation
DAI Shu-juan1, WEI De-zhou1, BAI Li-mei2, ZHOU Dong-qin1, WANG Yu-juan1, LIU Wen-gang1

1. School of Resources and Civil Engineering, Northeastern University, Shenyang 110004, China;
2. College of Resource and Environment, Hebei Polytechnic University, Tangshan 063009,China

Abstract:The adsorption regular of water-washing waste saccharomyces cerevisiae on cadmium in the wastewater of electroplating factory and sedimentation effect were studied by adsorption-sedimentation method using water-washing waste saccharomyces cerevisiae as adsorbent. The experimental results show that the adsorption rate and removing rate of cadmium are both above 96% under conditions with cadmium concentration in cadmium-containing electroplating wastewater about 26 mg/L, pH of 7.0, the dosage of water-washing waste saccharomyces cerevisiae of 40 g/L (about 72% water) at 18 ℃, the stiring revolution of 800 r/min, adsorption for 30 min and natural sedimentation for 3.5 h. The adsorption mechanism of water-washing waste saccharomyces cerevisiae to cadmium is analysized by TEM, Zeta potential and infrared spectroscopy of the cells. The results show that adsorbing effect occurs on the surface and inside of water-washing waste saccharomyces cerevisiae. The chemistry chelating, electrostatic force, hydrogen bonding and so on all fountion in the adsorption process.

 

Key words: electroplating wastewater; cadmium; water-washing waste saccharomyces cerevisiae; biosorption; sedimentation

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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