Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號:1004-0609(2008)10-1926-05
多組分稀土串級萃取有效分離系數(shù)的理論分析
鐘學明

(南昌航空大學 環(huán)境與化學工程學院,南昌 330063)

摘 要:

通過數(shù)學表達式研究多組分稀土串級萃取有效分離系數(shù)的理論規(guī)則,提出計算有效分離系數(shù)的平均分數(shù)法,對等效組分法、產(chǎn)品分數(shù)法和平均分數(shù)法計算結(jié)果進行理論分析。結(jié)果表明:有效分離系數(shù)存在極值規(guī)則、比例規(guī)則和權(quán)重規(guī)則;只有平均分數(shù)法完全遵循極值規(guī)則、比例規(guī)則和權(quán)重規(guī)則:平均分數(shù)法的計算結(jié)果,介于極大值和極小值之間,而且隨組分摩爾分數(shù)變化的趨勢是合理的:平均分數(shù)法計算的極值誤差為0;與等效組分法和產(chǎn)品分數(shù)法相比,在整個空間分布中平均分數(shù)法的準確度明顯更高。

 

關(guān)鍵字: 多組分;稀土;串級萃取;有效分離系數(shù);理論規(guī)則;平均分數(shù)法

Theoretical analysis of effective separation factor for multi-component rare earths in countercurrent extraction
ZHONG Xue-ming

School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China

Abstract:The theoretical rules for effective separation factor of multi-component rare earths in counter-current extraction were investigated by mathematical expression. The average fraction method to calculate effective separation factor was presented. Theoretical analyses were made to the calculation results by equivalent component method (EC), product fraction method (PF) and average fraction method (AF). The results show that there are Rule Extremum, Rule Proportion and Rule Weight for the factor. Only average fraction method could completely follow these three rules. The calculation results by average fraction method range between the maximum and minimum, and the movement trends of calculation results are in reason along with component mole fractions. The errors of extremums by average fraction method are 0. In the entire space range the average fraction method is much more accurate than the others.

 

Key words: multi-component; rare earth; countercurrent extraction; effective separation factor; theoretical rule; average fraction method

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學技術(shù)協(xié)會 主辦:中國有色金屬學會 承辦:中南大學
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學報》編輯部
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