Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號(hào):1004-0609(2008)10-1885-08
生物玻璃增強(qiáng)多孔羥基磷灰石生物陶瓷的制備及其性能
馬 莉,周科朝,李志友,黃蘇萍

(中南大學(xué) 粉末冶金國(guó)家重點(diǎn)實(shí)驗(yàn)室,長(zhǎng)沙 410083)

摘 要:

研究多孔羥基磷灰石(HA)生物陶瓷的制備方法及性能。采用顆粒尺寸為500~600 μm的炭粉,以體系為SiO2-Na2O-CaO-MgO-Al2O3的生物玻璃為高溫粘結(jié)劑,通過(guò)一定的混料、壓制和燒結(jié)工藝,可制得孔隙率為30%~48%,抗彎強(qiáng)度達(dá)11.65 MPa,大孔孔徑約500~600 μm、小孔孔徑1~20 μm并孔隙相互連通的多孔陶瓷。采用掃描電鏡(SEM)、X射線衍射儀(XRD)、電子萬(wàn)能實(shí)驗(yàn)機(jī)對(duì)樣品的微觀結(jié)構(gòu)和抗彎強(qiáng)度進(jìn)行分析,還通過(guò)分析天平,采用阿基米德原理對(duì)樣品孔隙率進(jìn)行測(cè)量。結(jié)果表明:隨著燒結(jié)溫度的升高,氣孔率逐漸減小,抗彎強(qiáng)度逐漸增加。通過(guò)控制炭粉的含量,可以有效的控制多孔燒結(jié)體的孔隙率、大孔的分布及孔徑。生物玻璃的加入可以促進(jìn)材料的液相燒結(jié),使多孔羥基磷灰石生物陶瓷致密化,改善其力學(xué)性能,同時(shí)隨著生物玻璃含量的增加孔隙率減少。

 

關(guān)鍵字: 羥基磷灰石;造孔劑;炭粉;多孔陶瓷;生物玻璃

Porous bioglass reinforced hydroxyapatite materials produced with carbon particles
MA Li, ZHOU Ke-chao, LI Zhi-you, HUANG Shu-ping

Key State Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Abstract: Carbon particles were used as pore formers to produce porous structures of a SiO2-Na2O- CaO-MgO-Al2O3 glass reinforced hydroxyapatite, and its microstructure and properties were studied. The experimental results show: that porous hydroxyapatite (HA) bioceramics can be obtained with porosity of 30%−48%, and the maximum bending strength of 11.65 MPa. Two separate range distributions of the pores size between 500−600 μm and 1−20 μm were observed. With the sintering temperature increasing, porosity decreases gradually, while bending strength increases. bioglass can improve the mechanical properties of materials, because bioglass will improve densification, thereby reducing porosity. By controlling the content of the carbon can effectively control the porosity, pore size and distribution of pore size. The final microstructure consists of hydroxyapatite, and β-tricalcium phosphate. X-ray diffraction analysis reveals different percentages of phases when porous glass reinforces hydroxyapatite specimens sintering at different temperatures. The biological response of these materials is yet to be tested.

 

Key words: porous hydroxyapatite; pore formers; carbon; porous ceramic; bioglass

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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