Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號:1004-0609(2008)10-1864-08
碳化硅陶瓷預(yù)制體的選區(qū)激光燒結(jié)及真空壓力滲鋁
徐志鋒,余 歡,鄭玉惠,蔡長春,嚴青松

(南昌航空大學(xué) 材料科學(xué)與工程學(xué)院,南昌330063)

摘 要:

提出采用選區(qū)激光燒結(jié)法(SLS)制備碳化硅(SiC)陶瓷預(yù)制體,探討SiC陶瓷表面改性對激光燒結(jié)成形性的影響,進行SiC陶瓷粉末的激光燒結(jié)成形工藝實驗,并對SiC陶瓷激光燒結(jié)件進行熱脫脂和真空壓力滲鋁。結(jié)果表明:SiC陶瓷表面經(jīng)硅烷偶聯(lián)劑KH-570(5%)改性處理后的激光燒結(jié)成形性得到很大的改善;同時,所添加粘結(jié)劑中的無機磷酸二氫氨含量控制在8%,其激光能量密度在0.10~0.12 J/mm2范圍內(nèi)均能燒結(jié)成形,而激光能量密度0.11 J/mm2的燒結(jié)件密度為2.31 g/cm3,抗彎強度達到0.81 MPa。對SiC陶瓷激光燒結(jié)件的熱脫脂和真空壓力滲鋁后的XRD和OM分析表明:脫脂過程中生成的SiP2O7是陶瓷預(yù)制體的新粘結(jié)劑;而真空浸滲過程中也僅有微量的AlPO4新生成相,并沒有其它的殘留物;且SiC陶瓷分布均勻,大小顆粒相互搭配,組織致密。此外,其外形形狀與CAD模型吻合,可實現(xiàn)SiCp/Al復(fù)合材料的近凈成形。

 

關(guān)鍵字: 碳化硅陶瓷;預(yù)制體;選區(qū)激光燒結(jié);表面改性;激光能量密度

Preform of SiC ceramic particles by SLS and vacuum-pressure infiltration of Aluminium
XU Zhi-feng, YU Huan, ZHENG Yu-hui, CAI Chang-chun, YAN Qing-song

School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

Abstract:A novel method for fabricating the silicon carbide ceramic preforms by using selective laser sintering (SLS) technology was proposed. The sintering properties with SiC surface modification, the sintering characteristic of SiC ceramic powders, and the debinding and infiltration process of SiC preforms were studied. The results show that the sintering characteristics of SiC ceramic powders with silane coupling reagent KH-570 are greatly improved. And then the contents of inorganic binder NH4H2PO4 are limited to 8%. The energy density is within the scope of 0.10−0.12 J/mm2. The density and bending strength of sintering samples under energy density of 0.11 J/mm2 is 2.31 g/cm3 and 0.81 MPa, separately. The prepared samples, when debinded and infiltrated, were characterized by XRD and OM. It can be inferred that the SiP2O7 is a sort of new binder in debinding samples, and a few of new AlPO4 phases are formed in the infiltrated process, and not only the composites dense but also SiC particles are distributed homogenously. In addition, the figure and size of prepared products are in accord with its CAD model.

 

Key words: silicon carbide ceramic; preforms; selective laser sintering; surface modification; laser energy density

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報》編輯部
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