Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報

ZHONGGUO YOUSEJINSHU XUEBAO

第18卷    第10期    總第115期    2008年10月

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文章編號:1004-0609(2008)10-1852-06
電流密度對無氰電鍍Au凸點生長行為的影響
米青霞,黃明亮,王 來

(大連理工大學(xué) 三束材料改性國家重點實驗室,材料科學(xué)與工程學(xué)院,大連 116024)

摘 要:

研究一種以氯金酸鈉為主鹽的無氰鍍金液在80 ℃、鍍液pH為8.0時陰極電流密度(J)對Au凸點生長行為的影響。結(jié)果表明:J在0.5~2.5 A/dm2范圍內(nèi)逐漸增大時,Au凸點生長速度單調(diào)增大;當(dāng)J=0.5~1.0 A/dm2時,所得Au凸點晶粒細(xì)小、表面平整、內(nèi)部致密;當(dāng)J=1.5~2.5 A/dm2時,隨著J的增大,凸點表面粗糙度逐漸增大,內(nèi)部致密度逐漸降低;從凸點橫截面形貌來看,在J=2.0 A/dm2時出現(xiàn)樹枝晶,在J=2.5 A/dm2時樹枝晶及晶間間隙已非常明顯。確定了該鍍液制作Au凸點的最佳電流密度為J=1.0 A/dm2。此時,平均凸點厚度與施鍍時間之間存在良好的線性關(guān)系。在蒸鍍Au種子層并刻蝕有圖形的Si基板上得到外形規(guī)整且與基板結(jié)合良好的Au凸點。

 

關(guān)鍵字: 無氰電鍍;鍍金;Au凸點;電流密度;生長行為

Effect of current density on growth behavior of Au bumps during non-cyanide electroplating
MI Qing-xia, HUANG Ming-liang, WANG Lai

State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

Abstract: The effect of current density (J) on the growth behavior of Au bumps in a stable non-cyanide gold electrolyte containing NaAuCl4∙2H2O was investigated under 80 ℃, pH 8.0. While J was in the range of 0.5~2.5 A/dm2, the higher the J was, the faster the Au bumps growth rate was. The results show that when J=0.5~1.0 A/dm2, the Au bumps have fine grains, high density and smooth surface. While J =1.5~2.5 A/dm2, the surface of the Au bumps becomes coarsing with increasing J value, whereas the density of the bumps keeps decreasing. Dendrites are clearly observed when J=2.0 A/dm2, and they become pronounced when J=2.5 A/dm2. Through the experiments, J=1.0 A/dm2 is chosen to electroplate Au bumps, under which a linear relationship exists between the average thickness of Au bumps and the electroplating time. Au bumps with regular shape and high adhesive strength with the Si substrate are obtained.

 

Key words: non-cyanide electroplating; Au electroplating; Au bump; current density; growth behavior

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
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