Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)

ZHONGGUO YOUSEJINSHU XUEBAO

第17卷    第3期    總第96期    2007年3月

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文章編號(hào):1004-0609(2007)03-0368-05
射頻反應(yīng)磁控濺射制備氮化銅薄膜
肖劍榮1, 2,徐 慧1,劉小良1,李燕峰1,張鵬華2,簡(jiǎn)獻(xiàn)忠3

(1. 中南大學(xué) 物理科學(xué)與技術(shù)學(xué)院,長(zhǎng)沙 410083;
2. 中南大學(xué) 材料科學(xué)與工程學(xué)院,長(zhǎng)沙 410083;
3. 上海理工大學(xué) 電氣工程學(xué)院,上海 200093
)

摘 要:

使用射頻反應(yīng)磁控濺射法,在不同的射頻功率和氣體流量比下制備了氮化銅薄膜,并用X射線衍射儀和原子力顯微鏡對(duì)薄膜的結(jié)構(gòu)進(jìn)行表征。研究結(jié)果表明:薄膜呈現(xiàn)擇優(yōu)生長(zhǎng)規(guī)律,由低氣體流量比的Cu3N(111)晶面轉(zhuǎn)向高分壓的(100)面;薄膜的光學(xué)帶隙在1.44~1.69 eV之間,電阻率在60~5.6×105 Ω∙m之間,二者都隨氣體流量比的增大而增大。

 

關(guān)鍵字: 氮化銅薄膜;晶體結(jié)構(gòu);光學(xué)帶隙;電阻率

Copper nitride thin films prepared by
radio frequency magnetron sputtering
XIAO Jian-rong1, 2, XU Hui1, LIU Xiao-liang1,
LI Yan-feng1, ZHANG Peng-hua2, JIAN Xian-zhong3

1. School of Physics Science and Technology, Central South University,Changsha 410083, China;
2. School of Material Science and Engineering, Central South University,Changsha 410083, China;
3. School of Electric and Engineering,University of Shanghai Science and Technology, ShangHai 200093, China

Abstract:Copper nitride (Cu3N) thin films were deposited by reactive radio frequency magnetron sputtering under different discharge powers and gas flow ratios. The structures of films were characterized by atomic force microscopy (AFM) and X-ray diffraction spectra (XRD). The properties of films were analyzed by UV-VIS spectra and four-probe method. The results show that the films’ growth prefers (111) direction at low nitrogen press and (100) direction at high nitrogen pressure. The optical band gap of the films ranges from 1.44 to 1.69 eV, the resistivity ranges from 60 to 5.6×105Ω∙m, and they both increase with the increase of nitrogen pressure.

 

Key words: copper nitride thin films; crystal structure; optical band gap; resistivity

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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