Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 22    Special 1    October 2012

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Determination of trap levels in CZT:In by thermally stimulated current spectroscopy
NAN Rui-hua1, JIE Wan-qi1, ZHA Gang-qiang1, BAI Xu-xu2, WANG Bei3, YU Hui1

1. State Key Laboratory of Solidification Processing, School of Materials Science and Engineering,
Northwestern Polytechnical University, Xi’an 710072, China;
2. Key Laboratory of Artificial Structures and Quantum Control, Ministry of Education,
Department of Physics, Shanghai Jiao Tong University, Shanghai 200240, China;
3. Science Institute, Air Force Engineering University, Xi’an 710051, China

Abstract:Many defects in semi-insulating (SI) cadmium zinc telluride (Cd1−xZnxTe or CZT) ingots grown by the melt methods act as trapping centers to introduce deep levels in the band gap, which has strong effects on CZT detection properties. The thermally stimulated current (TSC) spectroscopy was used to measure these traps, and the initial rise method and the simultaneous multiple peaks analysis (SIMPA) method were introduced to characterize trap levels in SI-CZT:In. The results show that there is a larger error in the determination for the trap peaks with the initial rise method due to the interference of overlapping peaks, while the SIMPA method demonstrates a better performance in resolving these overlapping peaks simultaneously for a full characterization of trap levels. On this basis, a theoretical SIMPA fitting, which is composed of ten trap levels and a deep donor level EDD dominating the dark current in SI-CZT:In, is achieved. Furthermore, the reason of high resistivity in CZT:In was explained by the relationship between EDD level and Fermi level.

 

Key words: Cd1−xZnxTe; trapping; deep levels; thermally stimulated current spectroscopy

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

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