Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國有色金屬學(xué)報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 22    No. 2    February 2012

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Synthesis of aluminum tri-polyphosphate anticorrosion
pigment from bauxite tailings
LU Qing-hua1, HU Yue-hua2

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China

Abstract:Aluminum tri-polyphosphate was synthesized from bauxite tailings and phosphoric acid with a P/Al molar ratio of 3. This is highly advantageous from a waste recycling perspective as bauxite tailings are generally regarded as unusable waste. The acidity, whiteness and mean particle size of prepared aluminum tri-polyphosphate are all improved after modification. The possibility of using modified aluminum tri-polyphosphate as an anticorrosive pigment was also investigated by electrochemical impedance spectroscopy. The resistance of the coatings with modified aluminum tri-polyphosphate is 7×107 Ω for 40 d of immersion, which is superior or at least comparable to that of coatings containing APW−2, which exhibits a resistance of 5.7×107 Ω.

 

Key words: aluminum tri-polyphosphate; waste processing; electrochemical impedance spectroscopy

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國科學(xué)技術(shù)協(xié)會 主辦:中國有色金屬學(xué)會 承辦:中南大學(xué)
湘ICP備09001153號 版權(quán)所有:《中國有色金屬學(xué)報》編輯部
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