中國有色金屬學報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 21 No. 6 June 2011 |
AB5-type hydrogen storage alloy modified with Co3O4
（1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China）
Abstract:Anodic electrodes with the mixture of hydrogen storage alloys and different contents of Co3O4 (2%, 4%, 6% and 8%, mass fraction) powders were made. The effects of Co3O4 on the electrochemical performance of the alloy electrodes were studied. The constant charge-discharge tests show that the discharge capacity of alloy electrodes with Co3O4 significantly increases, and the maximum discharge capacities of electrodes with 2%, 4%, 6% and 8% Co3O4 are higher than the electrode with no Co3O4 by 0.83%, 4.86%, 7.18% and 9.21%, accordingly. Linear polarization (LP) and electrochemical impedance spectroscopy (EIS) tests suggest that charge-transfer resistance decreases by the addition of Co3O4. Cyclic voltammogram (CV), scanning electron microscopy (SEM) and energy dispersive spectrum (EDS) tests indicate that Co3O4 can partly dissolve and experience a reversible oxidation-reduction process of Co to Co (OH)2, leading to the improvement in the electrochemical performance of hydrogen storage alloy.
Key words: Co3O4; hydrogen storage alloy; capacity; electrochemical performance
