中國有色金屬學報(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 17 Special 1 November 2007 |
anode material for lithium ion battery
ZHAO Ling-zhi(趙靈智)1, 2, HU She-jun(胡社軍)1, 3, RAO Mu-min(
（1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;
2. Faculty of Material and Energy, Guangdong University of Technology, Guangzhou 510090, China;
3. Department of Mathematics and Physics, Wuyi University, Jiangmen 529020, China）
Abstract:Tin carbon nanotube (Sn-CNTs) composite was prepared by ultrasonic-electrodepositing tin on the substrate of copper foil in a sulfate bath containing carbon nanotubes (CNTs). The composites were characterized by scanning electron microscopy (SEM), cyclic voltammetry(CV) and charge-discharge cycling test. The results show that Sn-CNTs have a better electrochemical performance than Sn. The capacity of Sn-CNTs is 843 mA∙h/g during the first discharge and the efficiency of charge-discharge reaches 85%. After 50 cycles, the capacity of Sn-CNTs keeps at 380 mA∙h/g. The CNTs in tin act as a structure supporter and play a role of an elastomer and conductive network, alleviating the electrode dilapidation resulted from volume change during the lithium insertion and deinsertion.
Key words: lithium ion battery; anode materials; electrodeposition; tin; carbon nanotube
