中國(guó)有色金屬學(xué)報(bào)(英文版)
Transactions of Nonferrous Metals Society of China
| Vol. 10 No. 2 April 2000 |
Effects of graphite on Zn-Sb alloys as anode
materials for lithium-ion batteries①
materials for lithium-ion batteries①
L Chun-ping(呂春萍), ZHAO Xin-bing(趙新兵),
CAO Gao-shao(曹高劭), ZHU Tie-jun(朱鐵軍)
CAO Gao-shao(曹高劭), ZHU Tie-jun(朱鐵軍)
（Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P.R.China）
Abstract:The electrochemical properties of multiphases Zn4Sb3C7and ZnSbC2as new lithium-ion anode materials were investigated. The composition and microstructures of these multiphase materials were analyzed by XRD and TEM. It was found that the addition of graphite modifies the microstructures of pure alloys. The capacities and the cycle stability of the anodes are greatly improved. The reversible capacity of Zn4Sb3C7reaches as high as 510 mAh/g at the first cycle, and keeps higher than 300 mAh/g after 10 charge/discharge cycles.
Key words: Zn4Sb3; ZnSb; multiphase anode material; lithium-ion battery
