Transactions of Nonferrous Metals Society of China The Chinese Journal of Nonferrous Metals

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中國(guó)有色金屬學(xué)報(bào)(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 18    No. 4    August 2008

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Effect of thermal treating temperature on characteristics of silver-doped titania
CHAI Li-yuan(柴立元)1, WEI Shun-wen(韋順文)1, PENG Bing(彭 兵)1, LI Zhu-ying(李竹英)2

1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;
2. Yiwu Bureau of Quality and Technical Supervision, Yiwu 322000, China

Abstract: The silver-doped titania antibacterial agent was synthesized by mixing silver nitrate and the precursor of titania. Effects of thermal treatment on the properties of the silver-doped titania powders were investigated by thermal gravimeter/differential thermal analyzer(TG/DTA), scanning electron microscope(SEM), and X-ray diffractometer(XRD), respectively. The results show that the anatase phase forms in titania when the powder is calcined at 400 ℃. With the increase of the calcination temperature from 400 to 700 ℃ , the grains of titania agglomerate and the particle size increases from 14 to 23 nm, and the specific surface area decreases from 63 to 38m2g. As the powder is calcined at 700 ℃, titania starts to transform from anatase to rutile phase. The release rate of silver ion of powder treated at the relatively low temperature is larger than that of powder treated at the relatively high temperature. The antibacterial tests show that the antibacterial activity of silver-doped titania powders is excellent against E.coli and S. aureus, and the antibacterial activity of powders weakens with the increase of the calcination temperature.

 

Key words: silver ion; titanium dioxide; antibacterial material

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW

主管:中國(guó)科學(xué)技術(shù)協(xié)會(huì) 主辦:中國(guó)有色金屬學(xué)會(huì) 承辦:中南大學(xué)
湘ICP備09001153號(hào) 版權(quán)所有:《中國(guó)有色金屬學(xué)報(bào)》編輯部
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