Abstract:In order to increase the modifying effect, the Cu-P master alloy was rapidly solidified with melt-spin method, and the nano-sized ribbon was gained at 105−106 ℃/s. Subsequently, ZL109 alloy was modified by nanocrystal and massive Cu-P master alloy, respectively, with molten metal casting method. The results show that the microscopic structure of ZL109 alloy modified by nanocrystal Cu-P master alloy is better than that modified by massive Cu-P master alloy, the original crystal silicon and eutectic silicon are refined more effectively and the mechanical properties are increased evidently: the tensile-strength is increased by 25%, the elongation is increased by 32.26% and the hardness is increased by 17.2%. Therefore, the melt-spin treatment is a feasible method to improve the modifying effect of Cu-P master alloy.

Key words: Cu-P master alloy; ZL109 alloy; melt-spin; rapid solidification; nanocrystal; modification; refinement