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中國有色金屬學(xué)報(英文版)

Transactions of Nonferrous Metals Society of China

Vol. 34 No. 9 September 2024

Micro-galvanic corrosion behaviour of Mg-(7,9)Al-1Fe-xNd alloys

Kai-xuan FENG¹, Tao LAI¹, Yang CHEN¹, Zheng YIN¹, Zhi-qin WU¹, Hong YAN¹, Hong-gun SONG¹, Chao LUO^1,2, Zhi HU¹

（1. School of Advanced Manufacturing, Nanchang University, Nanchang 330031, China;
2. Institute for Advanced Study, Nanchang University, Nanchang 330031, China）

Abstract:The localized micro-galvanic corrosion process and the kinetic information of Mg-(7,9)Al-1Fe-xNd alloys were investigated by in situ observation under electrochemical control and in situ atomic force microscopy (AFM) in an electrolyte environment. The results revealed that the formation of the Nd-rich phase in alloys resulted in a decrease in the Volta potential difference from ~400 mV (AlFe₃/α-Mg) to ~220 mV (Nd-rich/α-Mg), reducing the corrosion products around the cathodic phase and corrosion current density of the microscale area. The addition of Nd significantly improved the corrosion resistance, mainly due to the suppression of the micro-galvanic corrosion between the second phases and substrate. Finally, the corrosion mechanism of Mg-(7,9)Al-1Fe-xNd alloys was discussed based on in situ observations and electrochemical results.

Key words: magnesium alloy; scanning Kelvin probe force microscope; micro-galvanic corrosion; in situ observation; atomic force microscopy

ISSN 1004-0609
CN 43-1238/TG
CODEN: ZYJXFK

ISSN 1003-6326
CN 43-1239/TG
CODEN: TNMCEW